Search results for "Ozone layer"
showing 10 items of 10 documents
Contribution of Excited Ozone and Oxygen Molecules to the Formation of the Stratospheric Ozone Layer
2019
The absorption of UV, visible and near IR radiation by O3 produces transient, electronically excited O3. The absorption of thermal IR radiation ( = 9.065, 9.596 and 14.267 µm) produces vibrationally excited O3 molecules. Thermal absorption is likely the main factor in the self-decay of O3. Photoexcitation of ground state by IR and red light radiation produces singlet oxygens and . Chemical reactions in the stratosphere produce them as well. When reacting with ozone, singlet oxygen produces O (3P) and . By doing so, they tend to maintain the prevailing ozone concentration and are thereby important for the stability of the ozone layer. During the daytime, O(1D), and reach their maximum concen…
Analysing time-varying trends in stratospheric ozone time series using the state space approach
2014
Abstract. We describe a hierarchical statistical state space model for ozone profile time series. The time series are from satellite measurements by the Stratospheric Aerosol and Gas Experiment (SAGE) II and the Global Ozone Monitoring by Occultation of Stars (GOMOS) instruments spanning the years 1984–2011. Vertical ozone profiles were linearly interpolated on an altitude grid with 1 km resolution covering 20–60 km. Monthly averages were calculated for each altitude level and 10° wide latitude bins between 60° S and 60° N. In the analysis, mean densities are studied separately for the 25–35, 35–45, and 45–55 km layers. Model variables include the ozone mean level, local trend, seasonal osc…
Stratospheric Aerosols After Pinatubo: Results from the 1991/2 Airborne Arctic Stratospheric Expedition (AASE II)
1996
The Airborne Arctic Stratospheric Expedition II involved measurements of key quantities concerning the chemistry and physics of the stratospheric ozone loss from the NASA operated DC-8 and ER-2 platforms. The series of AASE II flights was conducted between August 22, 1991, until March 26, 1992, from Moffett Field (California), Fairbanks (Alaska), and Bangor (Maine). The timing and location of the AASE II flights permitted to obtain a large data basis pertaining to the effects of the Mt. Pinatubo volcanic plume spreading in the northern hemispheric stratosphere. This contribution presents results obtained from the ER-2 in-situ measurements up to altitudes of ≈ 20 km in the polar stratosphere…
Optical Sensor for Real-Time Detection of Trichlorofluoromethane
2019
Trichlorofluoromethane was once a promising and versatile applicable chlorofluorocarbon. Unaware of its ozone-depleting character, for a long time it was globally applied as propellant and refrigerant and thus led to significant thinning of the ozone layer and contributed to the formation of the so-called ozone hole. Although production and application of this substance were gradually reduced at an early stage, we still face the consequences of its former careless use. Today, trichlorofluoromethane is released during recycling processes of waste cooling devices, traded on the black market, and according to recent findings still illegally manufactured. Here, we present an optical sensor devi…
Strong influence of lowermost stratospheric ozone on lower tropospheric background ozone changes over Europe
2007
[1] Using ozone measurements from two sounding sites and two high-altitude stations in Central Europe, we show evidence for a dominant influence of changes in lowermost stratospheric ozone on the variability and overall upward trend of background ozone in the lower troposphere (3000–3500 m asl) during the 1992–2004 period. Numerical simulations with a stratospheric chemistry transport model suggest that changes in lower stratospheric ozone were driven by dynamics rather than by changes in stratospheric chlorine loading. In addition, Lagrangian model simulations indicate that changes in downward transport of ozone from the stratosphere into the troposphere were dominated by changes in lowerm…
UV Index Experimental Values During the Years 2000 and 2001 from the Spanish Broadband UV-B Radiometric Network¶
2007
An analysis is made of experimental ultraviolet erythemal solar radiation data measured during the years 2000 and 2001 by the Spanish UV-B radiation evaluation and prediction network. This network consists of 16 Robertson-Berger type pyranometers for evaluating solar erythemal radiation and five Brewer spectroradiometers for evaluating the stratospheric ozone. On the basis of these data the Ultraviolet Index (UVI) was evaluated for the measuring stations that are located either in coastal regions or in the more densely populated regions inland on the Iberian Peninsula. It has been checked that in most cases the maximum irradiance values corresponded to solar noon, although there were except…
Greenhouse Gas Emissions from Membrane Bioreactors
2017
Nowadays, it is widely accepted that wastewater treatment plants (WWTPs) are significant sources of greenhouse gas (GHG) emission, contributing to the anthropogenic sources. Among the GHG emitted from WWTPs, nitrous oxide (N2O) has been identified of having the major interest/concern, since its high global warming potential (GWP), is 298 times higher than that of CO2 and also to its capability to react with stratospheric ozone causing the layer depletion. Up to now, most of the experimental investigations have been carried out on conventional activated sludge (CAS) processes. The knowledge of N2O emission from advanced technologies such membrane bioreactors (MBRs) is still very limited. The…
On the radiative impact of aerosols on photolysis rates: comparison of simulations and observations in the Lampedusa island during the ChArMEx/ADRIME…
2016
The Mediterranean basin is characterized by large concentrations of aerosols from both natural and anthropogenic sources. These aerosols affect tropospheric photochemistry by modulating the photolytic rates. Three simulations of the atmospheric composition at basin scale have been performed with the CHIMERE chemistry-transport model for the period from 6 June to 15 July 2013 covered by the ADRIMED campaign, a campaign of intense measurements in the western Mediterranean basin. One simulation takes into account the radiative effect of the aerosols on photochemistry, the second one does not, and the third one is designed to quantify the model sensitivity to a bias in the ozone column. These s…
The Role of Excited Oxygen Molecules in the Formation of the Secondary Ozone Layer at 87 to 97 km
2018
The secondary ozone layer is located at elevations of 87 to 97 km in the upper mesosphere – lower thermosphere. It overlaps with the ionospheric D-layer. Daytime intensive UV radiation is dissociating O2 molecules to O atoms and photoexcitating O2 molecules up to 11.07eV level. Ozone photolysis between the wavelengths of 118.7–121.6 nm produces three oxygen atoms from one ozone molecule. Collision reactions of O2(B3 Σu —) and O2(X3 Σg —, υ≥26) with O2(X3 Σg —, υ=0) produce additional oxygen atoms. The number of oxygen atoms is maintained at such a high level that a small but significant ozone concentration survives. UV radiation weakens radically during the night. The number of O atoms show…
IEL.22-23-Unit 5. The Protection of the Atmosphere
2023
El document forma part dels materials docents presentants al Servei de Política Lingüística de la Universitat de València, convocatòria Premis Fernando Sapiña 2022 a la qüalitat lingüística en l’elaboració de materials docents en valencià i en anglès. UNIT 5.-THE PROTECTION OF THE ATMOSPHERE. 1. General aspects: Long-Range Transboundary Air Pollution Convention, 1979. 2. Vienna Convention for the Protection of the Ozone Layer. 3. Legal instruments regulating Climate Change: UNFCCC; Kyoto Protocol; Paris Agreement; COP26 - Glasgow Climate Pact